ROUTERA


Chapter 15 Polymers

Class 12th Chemistry Chapter Case Study


Case Study 1: Introduction to Polymers

Case: Polymers are large molecules formed by the combination of smaller units called monomers. The process of polymerization can occur in two main ways: addition polymerization and condensation polymerization. In addition polymerization, the monomers add to each other without the loss of any atom or molecule, while in condensation polymerization, two monomers join together with the elimination of a small molecule, often water. Polymers like polyethylene and polypropylene are formed through addition polymerization, whereas polymers like nylon-6,6 and polyester are formed by condensation polymerization. The structure and properties of the polymer depend on the type of polymerization, the nature of the monomers, and the reaction conditions.

Questions:

  1. Which of the following is an example of a polymer formed by addition polymerization?

    • A) Nylon-6,6
    • B) Polyethylene
    • C) Bakelite
    • D) Terylene
    • Answer: B) Polyethylene
  2. In condensation polymerization, which of the following is eliminated as a by-product?

    • A) Hydrogen
    • B) Oxygen
    • C) Water
    • D) Nitrogen
    • Answer: C) Water
  3. Which of the following polymers is formed by the polymerization of a single monomer?

    • A) Polystyrene
    • B) Nylon-6,6
    • C) Terylene
    • D) Bakelite
    • Answer: A) Polystyrene
  4. Which of the following is an example of a condensation polymer?

    • A) PVC
    • B) Polypropylene
    • C) Bakelite
    • D) Polymethyl methacrylate
    • Answer: C) Bakelite

Case Study 2: Types of Polymers

Case: Polymers are classified into two categories: thermoplastic and thermosetting polymers. Thermoplastics are polymers that can be melted and re-molded into different shapes, and they are not chemically cross-linked. Examples include polyethylene (used in plastic bags) and polystyrene (used in disposable cups). On the other hand, thermosetting polymers are polymers that, once set, cannot be re-melted and re-molded due to the presence of cross-links between the polymer chains. Examples include Bakelite (used in electrical insulators) and epoxy resins (used in adhesives).

Questions:

  1. Which of the following is an example of a thermoplastic polymer?

    • A) Bakelite
    • B) Polyethylene
    • C) Epoxy resin
    • D) Melamine
    • Answer: B) Polyethylene
  2. Which of the following polymers is a thermosetting polymer?

    • A) PVC
    • B) Teflon
    • C) Bakelite
    • D) Nylon
    • Answer: C) Bakelite
  3. Thermoplastic polymers can be easily molded or shaped because they:

    • A) Are chemically cross-linked
    • B) Are linear or branched and do not have strong intermolecular forces
    • C) Have a high melting point
    • D) Cannot be melted after polymerization
    • Answer: B) Are linear or branched and do not have strong intermolecular forces
  4. Which of the following properties is characteristic of thermosetting polymers?

    • A) They are soft and flexible
    • B) They can be melted and re-molded
    • C) They do not soften on heating
    • D) They are soluble in common solvents
    • Answer: C) They do not soften on heating

Case Study 3: Biodegradable Polymers

Case: With increasing environmental concerns over plastic waste, biodegradable polymers have gained significance in recent years. These polymers break down into simpler compounds over time due to microbial action or environmental factors. Examples of biodegradable polymers include polylactic acid (PLA) and polyhydroxyalkanoates (PHA). PLA is derived from renewable resources like corn starch and is used in biodegradable plastics. PHAs are produced by bacteria and can be used in medical and agricultural applications. Biodegradable polymers provide a solution to reduce the impact of plastic pollution.

Questions:

  1. Which of the following is an example of a biodegradable polymer?

    • A) Polyethylene
    • B) Polystyrene
    • C) Polyhydroxyalkanoates (PHA)
    • D) PVC
    • Answer: C) Polyhydroxyalkanoates (PHA)
  2. Polylactic acid (PLA) is obtained from:

    • A) Corn starch
    • B) Petroleum
    • C) Wood pulp
    • D) Coal
    • Answer: A) Corn starch
  3. The main advantage of biodegradable polymers over conventional plastics is:

    • A) They are cheaper to produce
    • B) They do not require high temperatures for processing
    • C) They break down into harmless substances over time
    • D) They are more durable and long-lasting
    • Answer: C) They break down into harmless substances over time
  4. Which of the following is NOT a property of biodegradable polymers?

    • A) They decompose naturally
    • B) They are made from renewable resources
    • C) They release toxic substances when degraded
    • D) They are used in medical applications
    • Answer: C) They release toxic substances when degraded

Case Study 4: Copolymers and Their Applications

Case: Copolymers are polymers made from two or more different types of monomers. They are classified into three main types: random copolymers, block copolymers, and alternating copolymers. Random copolymers have monomers arranged randomly, while block copolymers have large segments or blocks of one monomer repeated in the chain. Alternating copolymers alternate between two different monomers. Copolymers are designed to combine the properties of different monomers, resulting in materials with enhanced or specific properties. An example is Buna-S, a styrene-butadiene copolymer, used in the production of synthetic rubber.

Questions:

  1. Which of the following is an example of a copolymer used in the production of synthetic rubber?

    • A) PVC
    • B) Buna-S
    • C) Teflon
    • D) Bakelite
    • Answer: B) Buna-S
  2. Which of the following is a characteristic of block copolymers?

    • A) The monomers are arranged randomly
    • B) They consist of large blocks of different monomers
    • C) They alternate between two monomers
    • D) They are composed of a single type of monomer
    • Answer: B) They consist of large blocks of different monomers
  3. Random copolymers:

    • A) Have repeating blocks of different monomers
    • B) Have monomers arranged in a random manner along the polymer chain
    • C) Are composed of a single type of monomer
    • D) Have alternating monomers
    • Answer: B) Have monomers arranged in a random manner along the polymer chain
  4. Which of the following is true about copolymers?

    • A) They are made only from one type of monomer
    • B) They exhibit properties that are intermediate between those of the constituent monomers
    • C) They cannot be used for industrial applications
    • D) They are not stable at high temperatures
    • Answer: B) They exhibit properties that are intermediate between those of the constituent monomers

Case Study 5: Polymers in Medical Applications

Case: Polymers play a crucial role in the medical field, where they are used in a variety of applications, from drug delivery to prosthetics. Biocompatible polymers like poly(lactic acid) (PLA) and poly(glycolic acid) (PGA) are used to make sutures, surgical implants, and drug-delivery systems. These polymers can degrade over time, eliminating the need for surgical removal. Another example is the use of polyethylene in joint replacement implants due to its high wear resistance and biocompatibility. The use of biodegradable polymers ensures that medical devices can be safely absorbed or broken down by the body without long-term harmful effects.

Questions:

  1. Which of the following is used in the preparation of biodegradable sutures?

    • A) Polyethylene
    • B) Poly(lactic acid) (PLA)
    • C) PVC
    • D) Nylon
    • Answer: B) Poly(lactic acid) (PLA)
  2. Which property of polyethylene makes it suitable for joint replacement implants?

    • A) High chemical reactivity
    • B) High wear resistance
    • C) High solubility in water
    • D) High melting point
    • Answer: B) High wear resistance
  3. Biodegradable polymers are advantageous in medical applications because:

    • A) They can be easily molded into any shape
    • B) They do not require removal after use
    • C) They are cheaper to produce than synthetic polymers
    • D) They are highly durable and long-lasting
    • Answer: B) They do not require removal after use
  4. Poly(glycolic acid) (PGA) is used in medical applications because:

    • A) It is non-biodegradable
    • B) It is highly toxic
    • C) It is biodegradable and biocompatible
    • D) It is only used for synthetic rubber production
    • Answer: C) It is biodegradable and biocompatible