Assertion and Reason Questions Chapter-12 Atoms
Assertion (A) and other labelled Reason (R). Select the correct answer to these
questions from the options as given below.
A. Both A and R are true, and R is the correct explanation of A.
B. Both A and R are true, but R is not the correct explanation of A.
C. A is true, but R is false.
D. A is false, but R is true.
1. Assertion (A): An atom consists of a nucleus surrounded by
electrons.
Reason (R): The nucleus contains protons and neutrons that are
held together by strong nuclear forces.
- (a) Both A and R
are true, and R is the correct explanation of A.
-
Answer: (a)
Explanation: The structure of an
atom indeed consists of a nucleus with protons and neutrons, and the electrons
are arranged around it, which is explained by the strong nuclear forces acting
within the nucleus.
2. Assertion (A): The number of protons in an atom determines
its atomic number.
Reason (R): Atomic number is defined as the number of neutrons
present in the nucleus.
- (b) A is true, but
R is false.
-
Answer: (b)
Explanation: Atomic number is
defined as the number of protons in an atom, making R false since it incorrectly
defines atomic number.
3. Assertion (A): Isotopes of an element have the same number
of protons but different numbers of neutrons.
Reason (R): Isotopes exhibit different chemical properties due
to the difference in neutron number.
- (b) A is true, but
R is false.
-
Answer: (b)
Explanation: Isotopes do have the
same number of protons, but their chemical properties are primarily determined
by electron configuration, making R false.
4. Assertion (A): Electrons can occupy the same energy level in
an atom.
Reason (R): The Pauli exclusion principle states that no two
electrons can have the same set of quantum numbers.
- (a) Both A and R
are true, and R is the correct explanation of A.
-
Answer: (a)
Explanation: Electrons can share
the same energy level but must differ in their quantum states as per the Pauli
exclusion principle.
5. Assertion (A): An electron in a hydrogen atom can exist in
various energy levels.
Reason (R): The energy levels in an atom are quantized,
allowing only specific energies.
- (a) Both A and R
are true, and R is the correct explanation of A.
-
Answer: (a)
Explanation: The quantized nature
of energy levels in an atom permits electrons to occupy distinct energy states.
6. Assertion (A): The emission spectrum of hydrogen shows
discrete lines.
Reason (R): Electrons transition between fixed energy levels
when they emit energy.
- (a) Both A and R
are true, and R is the correct explanation of A.
-
Answer: (a)
Explanation: The discrete lines in
the emission spectrum result from electron transitions between quantized energy
levels in hydrogen.
7. Assertion (A): The ground state of an atom is its lowest
energy state.
Reason (R): Atoms in the ground state have electrons in the
highest energy levels.
- (b) A is true, but
R is false.
-
Answer: (b)
Explanation: The ground state is
indeed the lowest energy state, but electrons are in the lowest energy levels,
making R false.
8. Assertion (A): The ionization energy of an atom is the
energy required to remove an electron.
Reason (R): Ionization energy increases as the atomic number
increases.
- (b) A is true, but
R is false.
-
Answer: (b)
Explanation: While the assertion
about ionization energy is true, the trend in ionization energy varies; it
generally increases across a period but can decrease in some cases down a group,
making R false.
9. Assertion (A): The Bohr model of the atom explains the
quantized energy levels of electrons.
Reason (R): According to the Bohr model, electrons travel in
circular orbits around the nucleus.
- (a) Both A and R
are true, and R is the correct explanation of A.
-
Answer: (a)
Explanation: The Bohr model
effectively explains quantized energy levels, with electrons in fixed circular
orbits around the nucleus.
10. Assertion (A): The mass number of an element is the sum of
protons and neutrons in the nucleus.
Reason (R): Electrons contribute significantly to the mass of
the atom.
- (b) A is true,
but R is false.
-
Answer: (b)
Explanation: The mass number is
indeed the sum of protons and neutrons, but electrons contribute negligibly to
atomic mass, making R false.
11. Assertion (A): Atoms can lose or gain electrons to form
ions.
Reason (R): Ions are formed to achieve a stable electron
configuration, similar to noble gases.
- (a) Both A and R
are true, and R is the correct explanation of A.
-
Answer: (a)
Explanation: Atoms form ions by
losing or gaining electrons to attain stable configurations, often resembling
noble gases.
12. Assertion (A): The radius of an atom increases with the
addition of electrons in the same energy level.
Reason (R): Increased electron-electron repulsion in the same
energy level leads to expansion.
- (a) Both A and R
are true, and R is the correct explanation of A.
-
Answer: (a)
Explanation: Additional electrons
in the same energy level cause repulsion, leading to an increase in atomic
radius.
13. Assertion (A): The Rutherford model proposed that most of
the atom's volume is empty space.
Reason (R): Most of the atom's mass is concentrated in the
nucleus.
- (a) Both A and R
are true, and R is the correct explanation of A.
-
Answer: (a)
Explanation: The Rutherford model
indicates that a large part of the atom's volume is empty, with the mass
concentrated in a tiny nucleus.
14. Assertion (A): The energy required to remove an electron
from an atom is called electron affinity.
Reason (R): Electron affinity is typically positive for all
elements.
- (b) A is false,
but R is true.
-
Answer: (b)
Explanation: The correct term is
ionization energy, not electron affinity. Electron affinity can be either
positive or negative, making A false.
15. Assertion (A): Electrons in the same subshell have the same
energy.
Reason (R): Electrons are indistinguishable in an atom.
- (a) Both A and R
are true, and R is the correct explanation of A.
-
Answer: (a)
Explanation: Electrons within the
same subshell share energy levels, and their indistinguishable nature reinforces
this idea.
16. Assertion (A): An atom with an equal number of protons and
electrons is electrically neutral.
Reason (R): Protons are positively charged, while electrons are
negatively charged.
- (a) Both A and R
are true, and R is the correct explanation of A.
-
Answer: (a)
Explanation: The equal number of
positive protons and negative electrons results in a neutral charge.
17. Assertion (A): The stability of an atom is related to its
electron configuration.
Reason (R): Atoms with filled electron shells are more stable
than those with partially filled shells.
- (a) Both A and R
are true, and R is the correct explanation of A.
-
Answer: (a)
Explanation: Atoms with filled
shells exhibit greater stability due to lower energy states.
18. Assertion (A): The principal quantum number indicates the
size of an electron cloud.
Reason (R): A higher principal quantum number corresponds to a
larger electron cloud.
- (a) Both A and R
are true, and R is the correct explanation of A.
-
Answer: (a)
Explanation: As the principal
quantum number increases, the average distance of the electron cloud from the
nucleus increases, indicating larger size.
19. Assertion (A): The photoelectric effect is evidence of the
particle nature of light.
Reason (R): Photons must have sufficient energy to eject
electrons from a material.
- (a) Both A and R
are true, and R is the correct explanation of A.
-
Answer: (a)
Explanation: The necessity for
photons to have specific energy to cause photoelectric emission supports the
particle theory of light.
20. Assertion (A): The atomic mass of an element is not a whole
number.
Reason (R): Atomic mass is a weighted average of the masses of
all isotopes.
- (a) Both A and R
are true, and R is the correct explanation of A.
-
Answer: (a)
Explanation: Atomic mass is
averaged over all isotopes, often resulting in a non-integer value.
21. Assertion (A): Light can behave as both a wave and a
particle.
Reason (R): The dual nature of light is fundamental to quantum
mechanics.
- (a) Both A and R
are true, and R is the correct explanation of A.
-
Answer: (a)
Explanation: Quantum mechanics
describes light as having both wave-like and particle-like properties,
supporting A.
22. Assertion (A): The uncertainty principle applies to all
particles.
Reason (R): The principle states that it is impossible to know
both position and momentum of a particle simultaneously.
- (a) Both A and R
are true, and R is the correct explanation of A.
-
Answer: (a)
Explanation: The uncertainty
principle is a fundamental aspect of quantum mechanics affecting all particles.
23. Assertion (A): Quantum numbers are used to describe the
state of electrons in an atom.
Reason (R): Each electron in an atom can be described by a
unique set of four quantum numbers.
- (a) Both A and R
are true, and R is the correct explanation of A.
-
Answer: (a)
Explanation: Quantum numbers
provide a complete description of an electron's state, confirming R as the
explanation for A.
24. Assertion (A): Atomic orbitals are regions of space where
electrons are likely to be found.
Reason (R): Orbitals are defined by mathematical functions that
describe electron behavior.
- (a) Both A and R
are true, and R is the correct explanation of A.
-
Answer: (a)
Explanation: Orbitals represent
probabilities of finding electrons, as defined by their wave functions.
25. Assertion (A): The emission of photons from an atom occurs
when an electron drops to a lower energy level.
Reason (R): Photons carry energy away from the atom during this
transition.
- (a) Both A and R
are true, and R is the correct explanation of A.
-
Answer: (a)
Explanation: When electrons
transition to lower energy levels, they emit photons that correspond to the
energy difference.
26. Assertion (A): The principal quantum number can have values
of 0 and above.
Reason (R): The principal quantum number indicates the shell in
which an electron resides.
- (b) A is false,
but R is true.
-
Answer: (b)
Explanation: The principal quantum
number starts from 1, making A false, while R is true.
27. Assertion (A): The half-life of a radioactive isotope is
constant.
Reason (R): The half-life of an isotope depends on its chemical
environment.
- (b) A is true,
but R is false.
-
Answer: (b)
Explanation: The half-life is
indeed a constant property of a radioactive isotope and does not vary with
chemical environment, making R false.
28. Assertion (A): A neutron is more massive than a proton.
Reason (R): Neutrons contribute to the atomic mass more than
protons.
- (b) A is false,
but R is true.
-
Answer: (b)
Explanation: While the neutron is
indeed slightly more massive than the proton, the assertion is misleading, as
neutrons and protons are very close in mass.
29. Assertion (A): The kinetic energy of an electron in an atom
is quantized.
Reason (R): Electrons can only occupy certain allowed energy
levels in an atom.
- (a) Both A and R
are true, and R is the correct explanation of A.
-
Answer: (a)
Explanation: The quantization of
energy levels results in discrete kinetic energy values for electrons.
30. Assertion (A): Electromagnetic radiation consists of
oscillating electric and magnetic fields.
Reason (R): Electromagnetic waves do not require a medium to
propagate.
- (a) Both A and R
are true, and R is the correct explanation of A.
-
Answer: (a)
Explanation: Electromagnetic
radiation features oscillating fields that can propagate through a vacuum,
supporting both A and R.
31. Assertion (A): Heisenberg's uncertainty principle is a
fundamental concept in quantum mechanics.
Reason (R): The principle has practical implications for
measuring atomic properties.
- (a) Both A and R
are true, and R is the correct explanation of A.
-
Answer: (a)
Explanation: The uncertainty
principle is indeed central to quantum mechanics and impacts measurements at the
atomic level.
32. Assertion (A): The mass of an electron is negligible
compared to that of a proton or neutron.
Reason (R): This is why electrons are often ignored in atomic
mass calculations.
- (a) Both A and R
are true, and R is the correct explanation of A.
-
Answer: (a)
Explanation: The small mass of
electrons justifies their exclusion in atomic mass computations.
33. Assertion (A): The atomic structure of elements determines
their reactivity.
Reason (R): Elements with similar electron configurations
exhibit similar chemical properties.
- (a) Both A and R
are true, and R is the correct explanation of A.
-
Answer: (a)
Explanation: The atomic structure
indeed influences reactivity, as similar configurations lead to comparable
behaviors in chemical reactions.
34. Assertion (A): The mass defect in a nucleus results from
the binding energy.
Reason (R): Binding energy is the energy required to separate
nucleons in a nucleus.
- (a) Both A and R
are true, and R is the correct explanation of A.
-
Answer: (a)
Explanation: The mass defect
correlates to the binding energy necessary to overcome the forces holding the
nucleons together.
35. Assertion (A): Alpha particles are more massive than beta
particles.
Reason (R): Alpha particles consist of two protons and two
neutrons.
- (a) Both A and R
are true, and R is the correct explanation of A.
-
Answer: (a)
Explanation: The definition of
alpha particles as helium nuclei accounts for their greater mass compared to
beta particles.
36. Assertion (A): The quantum mechanical model of the atom
replaces the Bohr model.
Reason (R): The quantum mechanical model incorporates
wave-particle duality.
- (a) Both A and R
are true, and R is the correct explanation of A.
-
Answer: (a)
Explanation: The quantum mechanical
model's incorporation of wave properties indeed supersedes the Bohr model.
37. Assertion (A): Chemical bonds form due to interactions
between electrons.
Reason (R): Electrons determine the overall charge and
reactivity of an atom.
- (a) Both A and R
are true, and R is the correct explanation of A.
-
Answer: (a)
Explanation: The behavior of
electrons facilitates the formation of chemical bonds and governs atom
reactivity.
38. Assertion (A): The principal quantum number affects the
energy of an electron.
Reason (R): Higher principal quantum numbers correspond to
higher energy levels.
- (a) Both A and R
are true, and R is the correct explanation of A.
-
Answer: (a)
Explanation: Increased principal
quantum numbers correlate directly with higher energy states for electrons.
39. Assertion (A): Photons carry momentum as well as energy.
Reason (R): The momentum of a photon is related to its
wavelength.
- (a) Both A and R
are true, and R is the correct explanation of A.
-
Answer: (a)
Explanation: Photons indeed carry
momentum, with their momentum being inversely related to wavelength.
40. Assertion (A): The energy levels of electrons in an atom
are quantized.
Reason (R): Electrons can only occupy specific energy levels
without existing in between.
- (a) Both A and R
are true, and R is the correct explanation of A.
-
Answer: (a)
Explanation: The quantization of
electron energy levels allows for discrete energy states without intermediates.
41. Assertion (A): Nuclear fission releases a significant
amount of energy.
Reason (R): The binding energy per nucleon is higher in the
products than in the reactants.
- (a) Both A and R
are true, and R is the correct explanation of A.
-
Answer: (a)
Explanation: The release of energy
during fission is due to the increased binding energy per nucleon in the
resulting nucleus.
42. Assertion (A): The electron configuration of an atom
determines its position in the periodic table.
Reason (R): Elements with similar configurations belong to the
same group.
- (a) Both A and R
are true, and R is the correct explanation of A.
-
Answer: (a)
Explanation: The periodic table's
organization reflects electron configurations, placing similar elements in the
same groups.
43. Assertion (A): Ionization energy generally increases across
a period in the periodic table.
Reason (R): Increased nuclear charge leads to stronger
attraction between electrons and the nucleus.
- (a) Both A and R
are true, and R is the correct explanation of A.
-
Answer: (a)
Explanation: As nuclear charge
increases across a period, the effective nuclear attraction grows, necessitating
more energy for ionization.
44. Assertion (A): Quantum entanglement is a phenomenon
observed in particles.
Reason (R): Entangled particles exhibit correlations that
cannot be explained classically.
- (a) Both A and R
are true, and R is the correct explanation of A.
-
Answer: (a)
Explanation: The unique behavior of
entangled particles supports the assertion by illustrating non-classical
correlations.
45. Assertion (A): The strong nuclear force binds protons and
neutrons in the nucleus.
Reason (R): The strong force is stronger than the
electromagnetic force at very short distances.
- (a) Both A and R
are true, and R is the correct explanation of A.
-
Answer: (a)
Explanation: The strong nuclear
force effectively overcomes electromagnetic repulsion at close ranges, thus
binding nucleons together.
46. Assertion (A): The de Broglie wavelength of a particle is
inversely proportional to its momentum.
Reason (R): A higher momentum results in a shorter wavelength.
- (a) Both A and R
are true, and R is the correct explanation of A.
-
Answer: (a)
Explanation: The de Broglie
wavelength's inverse relationship with momentum supports the assertion.
47. Assertion (A): Isotopes of an element have the same number
of protons.
Reason (R): Isotopes differ only in their neutron count.
- (a) Both A and R
are true, and R is the correct explanation of A.
-
Answer: (a)
Explanation: The definition of
isotopes confirms that they share the same proton number, differing only in
neutrons.
48. Assertion (A): X-rays are a form of electromagnetic
radiation.
Reason (R): X-rays have higher energy and shorter wavelengths
than visible light.
- (a) Both A and R
are true, and R is the correct explanation of A.
-
Answer: (a)
Explanation: The classification of
X-rays as electromagnetic radiation is supported by their energy and wavelength
characteristics.
49. Assertion (A): Atomic mass is not always a whole number.
Reason (R): Atomic mass accounts for the average mass of an
element's isotopes.
- (a) Both A and R
are true, and R is the correct explanation of A.
-
Answer: (a)
Explanation: The averaging of
isotopic masses results in non-integer atomic masses.
50. Assertion (A): The photoelectric effect supports the
particle theory of light.
Reason (R): The effect demonstrates that light can eject
electrons from a metal surface.
- (a) Both A and R
are true, and R is the correct explanation of A.
-
Answer: (a)
Explanation: The photoelectric
effect's dependence on light frequency supports the idea of light behaving as
particles (photons).